Oxygen vacancy induced surface stabilization: (110) terminated magnetite
نویسندگان
چکیده
منابع مشابه
Subsurface cation vacancy stabilization of the magnetite (001) surface.
Iron oxides play an increasingly prominent role in heterogeneous catalysis, hydrogen production, spintronics, and drug delivery. The surface or material interface can be performance-limiting in these applications, so it is vital to determine accurate atomic-scale structures for iron oxides and understand why they form. Using a combination of quantitative low-energy electron diffraction, scannin...
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Scanning tunneling microscopy and photoemission spectroscopy have been used to determine the origin of the band-gap state in rutile TiO2(110). This state has long been attributed to oxygen vacancies (O{b} vac). However, recently an alternative origin has been suggested, namely, subsurface interstitial Ti species. Here, we use electron bombardment to vary the O{b} vac density while monitoring th...
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a r t i c l e i n f o From an interplay between variable temperature scanning tunneling microscopy and density–functional theory calculations, the evolution of oxygen chemisorption-induced surface reconstructions of the Cu(110) surface is determined. The surface reconstructions proceed via a sequential pathway with increasing oxygen surface coverage. The (2 × 1) reconstruction occurs first and ...
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The surface structure of (110) faceted strontium titanate nanoparticles synthesized via solvothermal method has been resolved using high-resolution electron microscopy (HREM). We demonstrate that the surface is a titania-rich structure containing tetrahedrally coordinated TiO4 units similar to the family of (n × 1) reconstructions observed on (110) surfaces of bulk crystalline strontium titanat...
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K. Fleischer, ∗ R. Verre, 2 O. Mauit, R. G. S. Sofin, L. Farrell, C. Byrne, C. M. Smith, J. F. McGilp, and I. V. Shvets. 1 School of Physics, Trinity College Dublin, Dublin 2, Ireland Department of Applied Physics, Chalmers University of Technology, 412 96 Göteborg, Sweden Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2, Ireland Departmen...
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2016
ISSN: 2469-9950,2469-9969
DOI: 10.1103/physrevb.94.165424